Heat Transfer Fluid

A good solar collector should last the life of the building.
The heat transfer fluid (HTF)
transports heat energy from solar collectors to the heat exchangers where
it is converted to domestic hot water and/or space heat. When we
select a HTF, we will be concerned with a) freezing point, b) boiling point,
c) corrosion inhibition, and d) toxicity, e) service life, and f) compatibility
with everything else in the system. Radiantec systems will use an
antifreeze solution as the HTF for the reasons below.
FREEZING POINT - A solution of
antifreeze and water can be used to prevent
damage from freezing conditions. A 30% solution is actually enough
to prevent freezing damage down to extremely low temperature because of
the particular way that antifreeze solutions freeze. As the temperature
drops, crystals of pure ice precipitate out of the antifreeze solution.
When this happens, the concentration of the remaining solution increases.
The result in a non-rigid slush that will not harm the solar collectors.
BOILING POINT - It is desirable to
specify a HTF which has a boiling temperature that is higher than the maximum temperature
and pressure that the collectors can reach under stagnation at so that
the pressure relief valve does not operate and vent HTF.
CORROSION INHIBITION - Glycol type
antifreezes tend to become acidic as
they age because a degradation product of glycol is glycolic acid. Acidity
is not good for heating systems because it promotes corrosion. An
antifreeze solution should have buffering compounds that will neutralize
any build-up of acids. When these buffering compounds are used up, acidity
will increase and the HTF should be replaced.
SERVICE LIFE - Your local automotive
shop or automotive supply store
will likely have test strips that will test for temperature protection,
acidity and reserve alkalinity. I would test at 1 week, 1 year, and every
5 years thereafter. If the antifreeze solution is not exposed to oxygen,
the solution might last more than 20 years, but test to be sure. This one
maintenance item will result in a solar system that lasts for the life
of the building.
TOXICITY - There are two
types of glycol antifreeze solutions commonly
available; ethylene glycol and propylene glycol. Ethylene glycol
has a lower freezing point and a higher boiling point than propylene glycol
Ethylene glycol is also moderately poisonous whereas propylene glycol is
used as a food additive and is commonly found in ice cream. Either material
is biodegradable and can be disposed of in a municipal or private sewage
disposal system. Either material will kill plants if applied directly.
Ethylene glycol might harm pets or wildlife if improperly disposed of.
Either material may cause bacterial bloom if disposed of in a body of water.
It is our opinion that ethylene glycol should not be used unless the chance
of contamination of the potable water is reduced to zero because the heating
system relief valve is set lower than the building water pressure.
COMPATIBILITY - The
HTF must be compatible with all other components in the
system. In particular, check the expansion tank bladder, any pump seals
and pump flange seals, seals in the air eliminator cap, etc. All Radiantec
materials are compatible.
HEAT CARRYING CAPACITY -
Glycols have a slightly lower heat capacity
than water. It is a common misconception that this fact requires the selection
of a larger pump to move the fluid faster as compensation. In fact, the
difference is miniscule. Bear in mind that the fluid will be 70% water anyway.
LUBRICATION - Glycol
has an oily consistency, and its use lubricates the
pump for even longer service life.
WHY NOT USE WATER AS THE HEAT TRANSFER FLUID? - Many
solar designs do this, particularly in milder climates. There are some cost savings,
but in our opinion they are not worth it. Some designs use mechanicals
to drain down the collectors whenever freezing conditions occur. These
mechanicals have to work flawlessly for over 40 years and sad experience
shows that they do not.
Another serious problem can
occur with drain downs if power fails in the middle of the day. Under stagnation,
the solar collectors go well above 212 degrees F. When the power comes
back on, a steam explosion can do considerable damage and present a safety
problem as well. It may not happen often, but it will happen someday.
Please remember that a solar
heating system will only pay itself back and benefit the environment if
it lasts a good long time. If something can go wrong with a mechanical
device, it surely will given enough time; and it only has to happen once.
You have to consider everything and you just cannot gloss over inconvenient
details. Whenever possible design your solar system so that nothing can
go wrong.
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